UV Curing
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UV curing (ultraviolet curing) is the process by which
ultraviolet light Ultraviolet (UV) is a form of electromagnetic radiation with wavelength from 10 nm (with a corresponding frequency around 30  PHz) to 400 nm (750  THz), shorter than that of visible light, but longer than X-rays. UV radiation i ...
is used to initiate a
photochemical Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400  nm), visible light (400–7 ...
reaction that generates a crosslinked network of
polymer A polymer (; Greek '' poly-'', "many" + ''-mer'', "part") is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic a ...
s. UV curing is adaptable to
printing Printing is a process for mass reproducing text and images using a master form or template. The earliest non-paper products involving printing include cylinder seals and objects such as the Cyrus Cylinder and the Cylinders of Nabonidus. The ea ...
,
coating A coating is a covering that is applied to the surface of an object, usually referred to as the Substrate (materials science), substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquid ...
, decorating,
stereolithography Stereolithography (SLA or SL; also known as vat photopolymerisation, optical fabrication, photo-solidification, or resin printing) is a form of 3D printing technology used for creating models, prototypes, patterns, and production parts in a lay ...
, and in the assembly of a variety of products and materials. In comparison to other technologies, curing with UV energy may be considered a low-temperature process, a high-speed process, and is a solventless process, as cure occurs via direct
polymerization In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer, monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are ...
rather than by
evaporation Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidi ...
. Originally introduced in the 1960s, this technology has streamlined and increased automation in many industries in the manufacturing sector.


Applications

UV curing is used in applications where there is a need for converting or curing
ink Ink is a gel, sol, or solution that contains at least one colorant, such as a dye or pigment, and is used to color a surface to produce an image, text, or design. Ink is used for drawing or writing with a pen, brush, reed pen, or quill. Thicker ...
s,
adhesive Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advant ...
s, and
coating A coating is a covering that is applied to the surface of an object, usually referred to as the Substrate (materials science), substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquid ...
s. UV-cured
adhesive Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advant ...
has become a high speed replacement for two-part adhesives, eliminating the need for solvent removal, ratio mixing, and potential life concern. It can be used in the
flexographic Flexography (often abbreviated to flexo) is a form of printing process which utilizes a flexible relief plate. It is essentially a modern version of letterpress, evolved with high speed rotary functionality, which can be used for printing on a ...
, offset, pad, and
screen printing Screen printing is a printing technique where a mesh is used to transfer ink (or dye) onto a substrate, except in areas made impermeable to the ink by a blocking stencil. A blade or squeegee is moved across the screen to fill the open mes ...
processes, where UV curing systems are used to polymerize images on screen-printed products, ranging from T-shirts to 3D and cylindrical parts. It is used in fine instrument finishing (guitars, violins, ukuleles, etc.), pool cue manufacturing and other wood craft industries. Printing with UV curable inks provides the ability to print on a very wide variety of substrates such as plastics, paper, canvas, glass, metal, foam boards, tile, films, and many other materials. Other industries that take advantage of UV curing include medicine, automobiles, cosmetics (for example artificial fingernails and gel nail polish), food, science, education, and art. UV curable inks have met the requirements of the publication sector on a variety of papers and boards.


Advantages of UV curing

A primary advantage of curing with ultraviolet light is the speed at which a material can be processed. Speeding up the curing or drying step in a process can reduce flaws and errors by decreasing time that an ink or coating spends wet. This can increase the quality of a finished item, and potentially allow for greater consistency. Another benefit to decreasing manufacturing time is that less space needs to be devoted to storing items which can not be used until the drying step is finished. Because UV energy has unique interactions with many different materials, UV curing allows for the creation of products with characteristics not achievable via other means. This has led to UV curing becoming fundamental in many fields of manufacturing and technology, where changes in strength, hardness, durability, chemical resistance, and many other properties are required.


Types of UV curing lamps


Medium-pressure lamps

Medium-pressure
mercury-vapor lamp A mercury-vapor lamp is a gas-discharge lamp that uses an electric arc through vaporized mercury to produce light. The arc discharge is generally confined to a small fused quartz arc tube mounted within a larger soda lime or borosilicate gl ...
s have historically been the industry standard for curing products with ultraviolet light. The bulbs work by sending an electric discharge to excite a mixture of mercury and
noble gas The noble gases (historically also the inert gases; sometimes referred to as aerogens) make up a class of chemical elements with similar properties; under standard conditions, they are all odorless, colorless, monatomic gases with very low chemi ...
es, generating a plasma. Once the mercury reaches a plasma state, it irradiates a high spectral output in the UV region of the
electromagnetic spectrum The electromagnetic spectrum is the range of frequencies (the spectrum) of electromagnetic radiation and their respective wavelengths and photon energies. The electromagnetic spectrum covers electromagnetic waves with frequencies ranging from ...
. Major peaks in light intensity occur in the 240-270  nm and 350-380 nm regions. These intense peaks, when matched with the absorption profile of a
photoinitiator A photoinitiator is a molecule that creates reactive species ( free radicals, cations or anions) when exposed to radiation (UV or visible). Synthetic photoinitiators are key components in photopolymers (for example, photo-curable coatings, adhesiv ...
, cause the rapid curing of materials. By modifying the bulb mixture with different gases and
metal halides Metal halides are compounds between metals and halogens. Some, such as sodium chloride are ionic, while others are covalently bonded. A few metal halides are discrete molecules, such as uranium hexafluoride, but most adopt polymeric structures, su ...
, the distribution of wavelength peaks can be altered, and material interactions are changed. Medium-pressure lamps can either be standard
gas-discharge lamp Gas-discharge lamps are a family of artificial light sources that generate light by sending an electric discharge through an ionized gas, a plasma. Typically, such lamps use a noble gas (argon, neon, krypton, and xenon) or a mixture of thes ...
s or
electrodeless lamp The induction lamp, electrodeless lamp, or electrodeless induction lamp is a gas-discharge lamp in which an electric or magnetic field transfers the power required to generate light from outside the lamp envelope to the gas inside. This is in co ...
s, and typically use an elongated bulb to emit energy. By incorporating optical designs such an elliptical or even
aconic reflector An aconic reflector refers to a light energy reflector that is not defined by a mathematical equation. Most light energy reflectors are based on conic sections such as parabolas, ellipses and circles. Aconic reflector is a generic term used to ...
, light can either be focused or projected over a far distance. These lamps can often operate at over 900 degrees Celsius and produce UV energy levels over 10 W/cm2.


Low-pressure lamps

Low-pressure mercury-vapor lamps generate primarily 254 nm 'UVC' energy, and are most commonly used in
disinfection A disinfectant is a chemical substance or compound used to inactivate or destroy microorganisms on inert surfaces. Disinfection does not necessarily kill all microorganisms, especially resistant bacterial spores; it is less effective than st ...
applications. Operated at lower temperatures and with less voltage than medium-pressure lamps, they, like all UV sources, require shielding when operated to prevent excess exposure of skin and eyes.


UV LED

Since development of the
aluminium gallium nitride Aluminium gallium nitride (AlGaN) is a semiconductor material. It is any alloy of aluminium nitride and gallium nitride. The bandgap of AlxGa1−xN can be tailored from 3.4eV (xAl=0) to 6.2eV (xAl=1). AlGaN is used to manufacture light-emitting d ...
LED in the early 2000s, UV LED technology has seen sustained growth in the UV curing marketplace. Generating energy most efficiently in the 365-405 nm 'UVA' wavelengths, continued technological advances, have allowed for improved electrical efficiency of UV LEDs as well as significant increases in output. UV LED lamps generate high energy directed to a specific area which strengthen the uniformity. Benefiting from lower-temperature operation and the lack of hazardous mercury, UV LEDs have replaced medium-pressure lamps in many applications. Major limitations include difficulties in designing optics for curing on complex three-dimensional objects, and poor efficiency at generating lower-wavelength energy, though development work continues.


See also

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Photopolymer A photopolymer or light-activated resin is a polymer that changes its properties when exposed to light, often in the ultraviolet or visible region of the electromagnetic spectrum. These changes are often manifested structurally, for example harden ...
*
UV stabilizers in plastics In polymer chemistry photo-oxidation (sometimes: oxidative photodegradation) is the degradation of a polymer surface due to the combined action of light and oxygen. It is the most significant factor in the weathering of plastics. Photo-oxidatio ...
*
Weather testing of polymers Accelerated photo-ageing of polymers in SEPAP units is the controlled polymer degradation and polymer coating degradation under lab or natural conditions. The prediction of the ageing of plastic materials is an important subject that concerns ...


References

{{Reflist Curing agents Ultraviolet radiation